394963
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394963
Aldrich
N,N-Dimethylformamide dimethyl acetal
derivatization grade
| Synonym: | 1,1-Dimethoxy-N,N-dimethylmethylamine, 1,1-Dimethoxytrimethylamine |
| CAS Number: | 4637-24-5 |
| Linear Formula: | (CH3)2NCH(OCH3)2 |
| Molecular Weight: | 119.16 |
| Beilstein Registry Number: | 506020 |
| EC Number: | 225-063-3 |
| MDL number: | MFCD00008482 |
| PubChem Substance ID: | 24864631 |
Description
| Application | Used in the preparation of formamidine derivatives,1,2 which are synthetic intermediates.3 |
| Used to catalyze the coupling of epoxides with carbon dioxide under solvent free conditions leading to cyclic carbonates.4 | |
| Packaging | 10×1 mL in ampule |
| 5, 25 mL in glass btl |
Properties
| grade | derivatization grade |
| refractive index | n |
| bp | 102-103 °C/720 mmHg(lit.) |
| density | 0.897 g/mL at 25 °C(lit.) |
Safety
| Hazard Codes | F,Xn |
| Risk Statements | 11-22-36/37/38 |
| Safety Statements | 16-26-36/37 |
| RIDADR | UN 3271 3/PG 2 |
| WGK Germany | 1 |
| Flash Point(F) | 41 °F |
| Flash Point(C) | 5 °C |
References
| Cited Reference | 1. Tet. 50, 2255, (1994) |
| 2. Synth. Commun. 24, 1617, (1994) | |
| 3. Aldrichimica Acta 18, 59, (1985) | |
| 4. Synth. Commun. 36, 3141, (2006) | |
| Fieser | Fieser 3,115 / Fieser 4,184 / Fieser 5,254 / Fieser 6,221 / Fieser 8,191 / Fieser 9,182 / Fieser 11,198 / Fieser 13,120 |
| reference | Aldrich MSDS 1, 771:A / Corp MSDS 1 (1), 1375:D / FT-IR 1 (1), 328:D / FT-IR 2 (1), 519:A / FT-NMR 1 (1), 528:C / IR-Spectra (3), 193:G / IR-Spectra (2), 174:F / NMR-Reference 2 (1), 285:C / RegBook 1 (1), 357:E / Sigma FT-IR 1 (2), 501:B / Structure Index 1, 49:A:7 / Vapor Phase 3, 418:D |
